Sodium percarbonate is a chemical compound formed by combining sodium carbonate (Na₂CO₃) and hydrogen peroxide (H₂O₂). Its chemical formula is 2Na₂CO₃·3H₂O₂. This specific structure gives it its unique properties. On contact with water, this compound spontaneously decomposes into two active components: sodium carbonate and hydrogen peroxide.
Decomposition on contact with water
As soon as sodium percarbonate comes into contact with moisture, it releases active oxygen in the form of microscopic bubbles. It is this release of oxygen that is the real ‘driving force’ behind its cleaning and whitening action.
The action of active oxygen
The oxygen released penetrates deep into the fibres of textiles and directly attacks the molecules responsible for stains and discolouration. It breaks the chemical bonds of these coloured compounds, transforming them into colourless particles that are easily rinsed away. This process, known as oxidation, helps to remove organic stains (sweat, food, cosmetics), eliminate accumulated detergent residues and restore textiles to their original whiteness.
Gentle on fabrics
Unlike harsh bleaching agents, sodium percarbonate is gentle on fibres. The oxygen it releases acts gradually and breaks down naturally into water and oxygen, leaving no chemical residues. It bleaches pigments without damaging textile fibres (unlike chlorine, which destroys cellulose).
The role of sodium percarbonate
At the same time, sodium carbonate (the other component produced by decomposition) helps to soften the water and optimises cleaning efficiency by maintaining a slightly alkaline pH, which is ideal for detergent action as it promotes the hydrolysis of fats. Under its influence, these fats are converted into soluble compounds (soaps), making them easier to remove.
This dual action explains its effectiveness in natural cleaning and its remarkable stain-removing properties.